Kapor who was unveiled on Thursday has been tasked to finish first in Zone III and qualify for the top-flight.
He has signed a two-year contract with the club owned by Wilfred Osei Kwaku, popularly known as Palmer, who was disqualified from contesting the 2019 Ghana Football Association presidential election.
Born in Serbia, Nebojsa Kapor holds a UEFA License A coaching certificate from Croatia Football Federation.
Tema Youth missed out on promotion by a whisker last season. Despite having the same points as Accra Lions, Tema Youth finished second because the former had a better head-to-head record.
Kapor previously worked as the Technical Directors for Football Schools and Camp Leotar Trebinje, Premier League- Bosnia, and also the head coach for University Football Team- Normal University, Hefei.
Tema Youth have collected six points from nine and are fifth on the log heading into matchday four this weekend.